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Polymorphism and isomorphism of Huperzine Asolvates: structure, properties and form transformation
Huperzine A is a monohydrate form (H1) occurring in nature and is marked under the same solid-state form. In our previous study, three Huperzine A polymorphs in its pure form were reported. During the process of crystal form screening, a remarkable property of Huperzine A was revealed: all crystals obtained from common solvents at room or lower temperatures were solvated forms and the anhydrous forms could only be prepared at 50 °C or higher temperatures.
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